Cobalt Tetraphenylporphine Electrocatalyzed N_2O Reduction in DMF Solution
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The electrocatalytic reduction of N<SUB>2</SUB>O in the presence of cobalt tetraphenylporphine (CoTPP) was investigated by means of cyclic voltammetry (CV). Based on the kinetical treatment of the data, the rate constant for the electron transfer to N<SUB>2</SUB>O from CoTPP dianion could be determined and the activation energy of the step was estimated as 39.5 kJ mol<SUP>−1</SUP>.
- Chemistry Letters
Chemistry Letters 1998(10), 1017-1018, 1998-10-05
The Chemical Society of Japan