Preparation of Diaza Dioxa Dithia Crown p-tert-Butylcalix[4]arene by S-Alkylation Reactions: Use of Metallo-Calix[4]arene Complexes as Reaction Templates

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<jats:title>Abstract</jats:title> <jats:p>New nickel-thiolato-calix[4]arene complexes were produced by mean of metal-template synthesis employing S-alkylation of a nickel thiolato complex with a dichloroethyl- or a dibromoethyl-calix[4]arene derivative. Demetallation of a nickel-thiolato-calix[4]arene complex resulted in a p-tert-butylcalix[4]arene derivative containing two N-, two O- and two S-donors.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 27 (10), 1037-1038, 1998-10-01

    Oxford University Press (OUP)

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