An Unusual Isotactic Coordination Polymer Chain Assembled by Mn (II) and O-phthalate : [Mn(μ-phth) (phen) (H_2O)_2]・H_2O (phth = o-phthalato ; phen = 1,10-phenanthroline)
The complex [Mn(μ-phth)(phen)(H<SUB>2</SUB>O)<SUB>2</SUB>]·H<SUB>2</SUB>O (phth = o-phthalato; phen = 1,10-phenanthroline), in which an unusual isotactic coordination polymer chain is assembled by Mn(II) and o-phthalate dianion, an amphiphilic channel which has hydrophilic inside and hydrophobic outside is formed via hydrogen bonds, has been isolated and structurally characterized.
- Chemistry letters
Chemistry letters 1998(10), 1051-1052, 1998-10-05
The Chemical Society of Japan