New Protocol for the Siteselective Alkylation and Vinylation of Aromatic Compounds. Catalyst-Specific Reactions

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著者

    • SATO Taisuke
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • TSUJIMOTO Takuya
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • CHATANI Naoto
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • MURAI Shinji
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

Catalyst-specific C-H/olefin as well as C-H/acetylene coupling has been accomplished for aromatics which contain both keto and imino substituents by simply changing the catalyst. By using Ru(H)<SUB>2</SUB>(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB> as the catalyst, the C-H bond at the position ortho to the carbonyl group reacted to add across an olefin. When Ru<SUB>3</SUB>(CO)<SUB>12</SUB> is used as the catalyst, the C-H bond at the position ortho to the imino group reacted with the olefin.

収録刊行物

  • Chemistry letters

    Chemistry letters 1998(10), 1053-1054, 1998-10-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004700355
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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