Mechanistic and IR Spectroelectrochemical Studies for Alkali Metal Ion Catalyzed Multiple Bond Metathesis Reactions of Carbon Dioxide

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著者

    • KIM Woo Young
    • Industrial Catalysis Research Lab., Korea Research Institute of Chemical Technology (KRICT)
    • CHANG Jong-San
    • Industrial Catalysis Research Lab., Korea Research Institute of Chemical Technology (KRICT)
    • PARK Sang-Eon
    • Industrial Catalysis Research Lab., Korea Research Institute of Chemical Technology (KRICT)

抄録

The reaction of the tetrakis(alkyl or aryl isocyanide) complex, Ni(CNR)<SUB>4</SUB> (R = 2,6-Me<SUB>2</SUB>C<SUB>6</SUB>H<SUB>3</SUB>, Me), with carbon dioxide in the presence of Li<SUP>+</SUP> leads to the formation of Ni(CO)<SUB>2</SUB>(CNR)<SUB>2</SUB> and the alkyl- or arylisocyanate, RN=C=O. <SUP>13</SUP>C-labeling studies indicate that the carbonyl ligands of Ni(CO)<SUB>2</SUB>(CNR)<SUB>2</SUB> are produced by multiple bond metatheses between CO<SUB>2</SUB> and CNR (R = 2,6-Me<SUB>2</SUB>C<SUB>6</SUB>H<SUB>3</SUB>, Me) not by deoxygenation of CO<SUB>2</SUB>.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(10), 1063-1064, 1998-10-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004700417
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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