Structural Diversity of Copper Complexes with 2,2'-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution
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Reaction of 2,2′-dipyridyldisulfide (dpds) with CuBr<SUB>2</SUB> in methanol provide a extended sheet or a discrete dimer structure. The discrete dimer [CuBr(dpds)]<SUB>2</SUB> change to the sheet structure of [CuBr(dpds)]<SUB>n</SUB> by heat in the solid state or prolonged standing in reaction system.
- Chemistry Letters
Chemistry Letters 1998(10), 1067-1068, 1998-10-05
The Chemical Society of Japan