Stereoselective Hydrolysis of p-Nitrophenyl Glycoside by Boronic Acid

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著者

    • OHE Takeru
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • KIDA Toshiyuki
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • ZHANG Wanbin
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • NAKATSUJI Yohji
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • IKEDA Isao
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

The alkaline hydrolysis of p-nitrophenyl α-D-glucoside, α-D-galactoside, and β-D-mannoside was selectively accelerated by addition of methyl boronic acid, as compared to that of the corresponding β-D-glucoside, β-D-galactoside, and α-D-mannoside. In the case of p-nitrophenyl α (or β)-D-glucoside, the α/β selectivity was increased up to 110 when four molar equivalents of methyl- or phenylboronic acid were added.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(11), 1077-1078, 1998-11-05 

    The Chemical Society of Japan

参考文献:  14件

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各種コード

  • NII論文ID(NAID)
    10004700528
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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