A Novel and Highly Effective Halogenation of Alkanes with Halides on Oxidation with m-Chloroperbenzoic Acid: Looks Old, but New Reaction

• Takahiko Kojima

  Department of Chemistry, Faculty of Science, Kyushu University

• Hidenobu Matsuo

  Department of Chemistry, Faculty of Science, Kyushu University

• Yoshihisa Matsuda

  Department of Chemistry, Faculty of Science, Kyushu University

抄録

The combination of tetraalkylammonium halides (Cl−, Br−) and m-chloroperbenzoic acid in CH3CN effectively halogenated alkanes accompanied by the formation of alkyl m-chlorobenzoate; for which the alkyl halides were formed via a non-photoinduced radical mechanism and the esters were derived from a non-radical process and concomitant with the formation of corresponding trialkylamine.

収録刊行物

• Chemistry Letters

  Chemistry Letters 27 (11), 1085-1086, 1998-11-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694086148736
• NII論文ID: 10004700606
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1998.1085
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/27/11/1085/56073371/cl.1998.1085.pdf
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