Enantioselective Borohydride 1,4-Reduction of α,β-Unsaturated Carboxamides Using Optically Active Cobalt (II) Complex Catalysts

この論文にアクセスする

この論文をさがす

著者

    • YAMADA Tohru
    • Department of Chemistry, Faculty of Science and Technology, Keio University
    • OHTSUKA Yuhki
    • Department of Chemistry, Faculty of Science and Technology, Keio University
    • IKENO Taketo
    • Department of Chemistry, Faculty of Science and Technology, Keio University

抄録

The enantioselective borohydride reduction catalyzed by cobalt(II) complex was successfully applied to 1,4-reduction of β,β-disubstituted α,β-unsaturated carboxamides. In the presence of less than 1 mol% of optically active aldiminato cobalt(II) complex catalyst, the corresponding carboxamides were obtained in high yields with high enantiomeric excesses.

収録刊行物

  • Chemistry letters

    Chemistry letters 1998(11), 1129-1130, 1998-11-05

    The Chemical Society of Japan

参考文献:  9件中 1-9件 を表示

  • <no title>

    NAGATA T.

    Angew. Chem. Int. Ed. Engl. 34, 2145, 1995

    被引用文献24件

  • <no title>

    SUGI K. D.

    Chem. Lett. 1996, 737,1081

    被引用文献1件

  • <no title>

    NAGATA T.

    Synlett 1996, 1076

    被引用文献5件

  • <no title>

    SUGI K. D.

    Chem. Lett. 1997, 493

    被引用文献9件

  • <no title>

    FRITSCHI H.

    Helv. Chim. Acta 71, 1541, 1988

    被引用文献1件

  • <no title>

    FRITSCHI H.

    Helv. Chim. Acta 71, 1553, 1988

    被引用文献7件

  • <no title>

    LEUTENEGGER U.

    Angew. Chem., Int. Ed. Engl. 28, 60, 1989

    被引用文献3件

  • <no title>

    von MATT P.

    Tetrahedron: Asym. 2, 691, 1991

    被引用文献1件

  • <no title>

    SOAI K.

    J. Org. Chem. 51, 4000, 1986

    被引用文献5件

各種コード

  • NII論文ID(NAID)
    10004700914
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ