Enantioselective Borohydride 1,4-Reduction of α, β-Unsaturated Carboxamides Using Optically Active Cobalt(II) Complex Catalysts

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  • Tohru Yamada
    Department of Chemistry, Faculty of Science and Technology, Keio University
  • Yuhki Ohtsuka
    Department of Chemistry, Faculty of Science and Technology, Keio University
  • Taketo Ikeno
    Department of Chemistry, Faculty of Science and Technology, Keio University

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<jats:title>Abstract</jats:title> <jats:p>The enantioselective borohydride reduction catalyzed by cobalt(II) complex was successfully applied to 1,4-reduction of β,β-disubstituted α,β-unsaturated carboxamides. In the presence of less than 1 mol% of optically active aldiminato cobalt(II) complex catalyst, the corresponding carboxamides were obtained in high yields with high enantiomeric excesses.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 27 (11), 1129-1130, 1998-11-01

    Oxford University Press (OUP)

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