Investigations of the Thermal Inversion Rates of Azobenzenes in Supercritical and Gaseous CO_2 : A Shift from the Energy-Transfer-Limited to the TST-Valid Region at Low Densities
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Studies of slow thermal Z/E isomerization reactions around the N=N double bond of azobenzenes in supercritical and gaseous carbon dioxide revealed that a shift from the energy-transfer-limited to the TST-valid region predicted by Kramers takes place at relatively low densities.
- Chemistry Letters
Chemistry Letters 1998(11), 1159-1160, 1998-11-05
The Chemical Society of Japan