Investigations of the Thermal Inversion Rates of Azobenzenes in Supercritical and Gaseous CO_2 : A Shift from the Energy-Transfer-Limited to the TST-Valid Region at Low Densities
Studies of slow thermal Z/E isomerization reactions around the N=N double bond of azobenzenes in supercritical and gaseous carbon dioxide revealed that a shift from the energy-transfer-limited to the TST-valid region predicted by Kramers takes place at relatively low densities.
- Chemistry letters
Chemistry letters 1998(11), 1159-1160, 1998-11-05
The Chemical Society of Japan