Investigations of the Thermal Inversion Rates of Azobenzenes in Supercritical and Gaseous CO_2 : A Shift from the Energy-Transfer-Limited to the TST-Valid Region at Low Densities

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著者

    • USUI Toshinori
    • Department of Chemistry and Physics, Graduate School of Science, Nagoya University
    • TAKAGI Hideo D
    • Department of Chemistry and Physics, Graduate School of Science, Nagoya University
    • ASANO Tsutomu
    • Department of Applied Chemistry, Faculty of Engineering, Oita University

抄録

Studies of slow thermal Z/E isomerization reactions around the N=N double bond of azobenzenes in supercritical and gaseous carbon dioxide revealed that a shift from the energy-transfer-limited to the TST-valid region predicted by Kramers takes place at relatively low densities.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1998(11), 1159-1160, 1998-11-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004701113
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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