Biocatalytic One-step Synthesis of <i>n</i>-Octyl <i>β</i>-<scp>d</scp>-Xylotrioside and Xylobioside from Xylan and <i>n</i>-Octanol in Supercritical Carbon Dioxide

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  • Matsumura Shuichi
    Department of Applied Chemistry, Faculty of Science and Technology, Keio University
  • Nakamura Takehiro
    Department of Applied Chemistry, Faculty of Science and Technology, Keio University
  • Yao Eiya
    Department of Applied Chemistry, Faculty of Science and Technology, Keio University
  • Toshima Kazunobu
    Department of Applied Chemistry, Faculty of Science and Technology, Keio University

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タイトル別名
  • Biocatalytic One-step Synthesis of <I>n</I>-Octyl <I>β</I>-<FONT SIZE="-2">D</FONT>-Xylotrioside and Xylobioside from Xylan and <I>n</I>-Octanol in Supercritical Carbon Dioxide

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n-Octyl β-D-xylotrioside and xylobioside, which are effective next generation surfactants, can be prepared by the one-step reaction of xylan and n-octanol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145) as the enzyme source of xylanase in supercritical carbon dioxide (scCO2). Yields of the octyl glycosides were significantly increased using scCO2. Furthermore, without scCO2, n-octyl xylotrioside was hardly produced.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 28 (7), 581-582, 1999

    公益社団法人 日本化学会

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