New Findings in Photochemistry of p-Nitrophenyl Azide in the Presence of an Amine:Generation and Trapping of Enamines

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著者

    • MURATA Shigeru
    • Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo
    • MORI Yoko
    • Chemistry Department for Materials, Faculty of Engineering, Mie University
    • SATOH Youji
    • Chemistry Department for Materials, Faculty of Engineering, Mie University
    • TOMIOKA Hideo
    • Chemistry Department for Materials, Faculty of Engineering, Mie University

抄録

4,5-Dihydro-5-diethylamino-1-(<I>p</I>-nitrophenyl)-1,2,3-triazole (<B>3</B>) was obtained in the photolysis of <I>p</I>-nitrophenyl azide (<B>1</B>) in triethylamine (TEA), for which the structure was determined by X-ray crystallographic analysis. The formation of the triazoline <B>3</B> is reasonably explained in terms of trapping of <I>N,N</I>-diethylvinylamine (<B>5</B>) generated <I>in situ</I> with the starting azide <B>1</B>. The reaction sequence involving a single electron transfer from TEA to the electronically excited azide is proposed for the formation of the enamine <B>5</B>.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(7), 597-598, 1999-07-05 

    The Chemical Society of Japan

参考文献:  26件

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各種コード

  • NII論文ID(NAID)
    10004701801
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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