Incorporation of La3+ in an Organic Network. A Polyphenol-Derived Solid Brønsted-Base Catalyst

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  • Toshiyuki Saiki
    CREST, Japan Science and Technology Corporation (JST), Institute for Fundamental Research of Organic Chemistry, Kyushu UniversityHakozaki, Higashi-ku, Fukuoka
  • Yasuhiro Aoyama
    CREST, Japan Science and Technology Corporation (JST), Institute for Fundamental Research of Organic Chemistry, Kyushu UniversityHakozaki, Higashi-ku, Fukuoka

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<jats:title>Abstract</jats:title> <jats:p>Treatment of anthracenebisresorcinol 1 (a tetraphenol) with La(OiPr)3 in THF affords an amorphous 1:2 (14− to La3+) coordination polymer (La host). It catalyzes typical base-promoted reactions such as Michael, nitroaldol, and, less effectively, aldol reactions, where the insoluble catalyst (La host) can be readily recovered and repeatedly used.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 28 (8), 797-798, 1999-08-01

    Oxford University Press (OUP)

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