Copper(I) Iodide-Promoted Allylation of Allyl-and Vinyl-silanes Assisted by Intramolecular-Coordination

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著者

    • TAKEDA Takeshi
    • Department of Applied Chemistry, Tokyo University of Agriculture and Technology
    • URUGA Tetsuya
    • Department of Applied Chemistry, Tokyo University of Agriculture and Technology
    • GOHROKU Kazushi
    • Department of Applied Chemistry, Tokyo University of Agriculture and Technology
    • FUJIWARA Tooru
    • Department of Applied Chemistry, Tokyo University of Agriculture and Technology

抄録

The allylation products, 1-(2-pyridylthio)alk-1,5-dienes, were produced regioselectively when 1-(2-pyridylthio)-1-(trimethylsilyl)alk-2-enes were treated with allylic chlorides in the presence of CuI and KF. The similar reaction of 1-(2-pyridylthio)-1-(trimethylsilyl)alk-1-enes with allylic chlorides produced the 1,4-dienes with complete retention of configuration.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(8), 821-822, 1999-08-05 

    The Chemical Society of Japan

参考文献:  13件

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各種コード

  • NII論文ID(NAID)
    10004703495
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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