Methylenation of Esters with Bis(iodozincio)methane-TiCl2-TMEDA System

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  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto UniversityYoshida, Sakyo-ku, Kyoto
  • Katsumi Ukai
    Department of Material Chemistry, Graduate School of Engineering, Kyoto UniversityYoshida, Sakyo-ku, Kyoto
  • Tsuyoshi Mizuno
    Department of Material Chemistry, Graduate School of Engineering, Kyoto UniversityYoshida, Sakyo-ku, Kyoto
  • Kiitiro Utimoto
    Department of Material Chemistry, Graduate School of Engineering, Kyoto UniversityYoshida, Sakyo-ku, Kyoto

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<jats:title>Abstract</jats:title> <jats:p>Methylenation of ester carbonyl group with bis(iodozincio)methane was examined: a use of TiCl2 and amine as mediators facilitated the reaction to give vinyl ethers in good yields.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 28 (8), 825-826, 1999-08-01

    Oxford University Press (OUP)

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