New Stable Metallic Salt Based on a Donor Molecule Containing peri-Ditellurium Bridges, TMTTeN(SCN)_<0.88>

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著者

    • OJIMA Emiko
    • School of Mathematical and Physical Science, The Graduate University for Advanced Studies and Institute for Molecular Science
    • NERYMBETOV Bakhyt Zh.
    • School of Mathematical and Physical Science, The Graduate University for Advanced Studies and Institute for Molecular Science
    • FUJIWARA Hideki
    • School of Mathematical and Physical Science, The Graduate University for Advanced Studies and Institute for Molecular Science
    • KOBAYASHI Hayao
    • School of Mathematical and Physical Science, The Graduate University for Advanced Studies and Institute for Molecular Science
    • KOBAYASHI Akiko
    • Department of Chemistry, School of Science, The University of Tokyo
    • TAKIMIYA Kazuo
    • Department of Applied Chemistry, Faculty of Engineering, Hiroshima University
    • OTSUBO Tetsuo
    • Department of Applied Chemistry, Faculty of Engineering, Hiroshima University
    • OGURA Fumio
    • Department of Industrial Chemistry, Faculty of Engineering, Kinki University

抄録

A new stable organic metal, TMTTeN(SCN)<SUB>0.88</SUB>, where TMTTeN is 2,3,6,7-tetramethylnaphtho[1,8-<I>cd</I>:4,5-<I>c</I>′<I>d</I>′]bis[1,2] ditellurole, was obtained. The donors are stacked to form columns and three-dimensional network is developed through Te···Te contacts. The salt is highly conductive and keeps metallic behavior down to 4.2 K. Furthermore the salt exhibits Pauli paramagnetic behavior down to 2 K. The extended Hückel tight-binding band calculation was examined.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(8), 845-846, 1999-08-05 

    The Chemical Society of Japan

参考文献:  12件

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各種コード

  • NII論文ID(NAID)
    10004703737
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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