Photoreduction of N, N'-Bridged Porphyrins to 20π Antiaromatic Isophlorins

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著者

    • SETSUNE Jun-ichiro
    • Department of Chemistry, Faculty of Science, and Graduate School of Science and Technology, Kobe University
    • KASHIHARA Kenji
    • Department of Chemistry, Faculty of Science, and Graduate School of Science and Technology, Kobe University
    • WADA Ken-ichi
    • Department of Chemistry, Faculty of Science, and Graduate School of Science and Technology, Kobe University

抄録

20π Antiaromatic isophlorins of <I>N</I><SUP><I>21</I></SUP>,<I>N</I><SUP><I>22</I></SUP>-bridged <I>N</I><SUP><I>23</I></SUP>-alkyl-porphyrins were prepared through photoreduction with N-benzyl-1,4dihydronicotinamide or intramolecular nucleophilic alkylation at the N(24)-position. The ring structure of these <I>N</I><SUP><I>21</I></SUP>,<I>N</I><SUP><I>22</I></SUP>-bridged isophlorins is not highly deviated from planarity and their antiaromaticity was indicated by the great paramagnetic ring current effect.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(8), 847-848, 1999-08-05 

    The Chemical Society of Japan

参考文献:  16件

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各種コード

  • NII論文ID(NAID)
    10004703750
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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