Synthesis and Structure of Tetrakis Carboxylato-Bridged Dinuclear Manganese(II)Quinoline Complexes, with Carboxylates Diphenylacetate and 2, 2-Diphenylpropanoate

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著者

    • NAKASHIMA Michio
    • Department of Chemistry, Faculty of Science and Engineering, Saga University
    • MARUO Hiroshi
    • Department of Chemistry, Faculty of Science and Engineering, Saga University
    • HATA Tetsuya
    • Department of Chemistry, Faculty of Science and Engineering, Saga University
    • TOKII Tadashi
    • Department of Chemistry, Faculty of Science and Engineering, Saga University

抄録

Two dinuclear Mn(II) quinoline complexes with diphenylacetate <B>1</B> or 2,2-diphenylpropanoate <B>2</B> have been prepared. Single crystal X-ray crystallography revealed the molecular structure to be the form of copper(II) acetate's. Bonding distances Mn-Mn, Mn-O, and Mn-N for <B>1</B> are 3.131(2), 2.116, and 2.193(5) Å, respectively, and those for <B>2</B> are 3.168(4), 2.117, and 2.215(4) Å, respectively. Anomalousness of Mn-Mn magnetic interaction of this type complexes is demonstrated.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(12), 1277-1278, 1999-12-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004703931
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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