Rh_4S_7 and Ir_3CuS_6 Clusters with Di-and Trisulfido Ligands Derived from Dinuclear Hydrogensulfido Complexes

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著者

    • KOCHI Takuya
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
    • TANABE Yoshiaki
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
    • TANG Zhen
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
    • ISHII Youichi
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
    • HIDAI Masanobu
    • Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

抄録

Reactions of the dinuclear hydrogensulfido-bridged complexes [Cp<SUP>*</SUP>MCl(μ-SH)<SUB>2</SUB>MClCp<SUP>*</SUP>] (M = Rh, Ir) with CuCl<SUB>2</SUB>·2H<SUB>2</SUB>O lead to formation of Rh<SUB>4</SUB>S<SUB>7</SUB> and Ir<SUB>3</SUB>CuS<SUB>6</SUB> clusters [(Cp<SUP>*</SUP>Rh)<SUB>4</SUB>(μ<SUB>3</SUB>-S<SUB>2</SUB>)<SUB>2</SUB>(μ<SUB>4</SUB>-S<SUB>3</SUB>)][CuCl<SUB>2</SUB>]<SUB>2</SUB> and [(Cp<SUP>*</SUP>Ir)<SUB>3</SUB>(μ<SUB>3</SUB>-S<SUB>2</SUB>)<SUB>3</SUB>(CuCl<SUB>2</SUB>)][CuCl<SUB>2</SUB>] through the oxidative S–S bond formation, the former of which contains a trisulfido ligand of the unprecedented μ<SUB>4</SUB>-η<SUP>2</SUP>:η<SUP>1</SUP>:η<SUP>1</SUP>:η<SUP>1</SUP> coordination mode.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1279-1280, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004703938
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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