Chemical Ionization of n-Paraffins(C_<14>-C_<18>)by CH^+_5, C_2H^+_5, and C_3H^+_5 in an Ion-Trap Type of Mass Spectrometer

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著者

    • TANAKA Yuki
    • Institute of Advanced Material Study, Kyushu University
    • ARIKAWA Takeshi
    • Department of Applied Science for Electronics and Materials, Graduate School of Engineering Sciences, Kyushu University

抄録

Chemical ionization of <I>n</I>-paraffins (C<SUB>n</SUB>H<SUB>2n+2</SUB> : n = 14∼18) by the CH<SUB>5</SUB><SUP>+</SUP>, C<SUB>2</SUB>H<SUB>5</SUB><SUP>+</SUP>, and C<SUB>3</SUB>H<SUB>5</SUB><SUP>+</SUP> ions has been studied using an ion-trap type of GC/MS under a reactant-ion-selected mode. In all the reactions, C<SUB>n</SUB>H<SUB>2n+1</SUB><SUP>+</SUP> and C<SUB>m</SUB>H<SUB>2m+1</SUB><SUP>+</SUP> (m = 3∼n−3) ions were observed. The most favorable fragment C<SUB>m</SUB>H<SUB>2m+1</SUB><SUP>+</SUP> ion in the CH<SUB>5</SUB><SUP>+</SUP> reaction was m = 8, while that in the C<SUB>2</SUB>H<SUB>5</SUB><SUP>+</SUP> and C<SUB>3</SUB>H<SUB>5</SUB><SUP>+</SUP> reactions was m = n−5 or n−6.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1281-1282, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004703971
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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