A New Process for C-Si Bond Formation from cis-Alkyl(silyl)platinum(II)Complexes

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著者

    • OZAWA Fumiyuki
    • Department of Applied Chemsitry, Faculty of Engineering, Osaka City University
    • KITAGUCHI Masaya
    • Department of Applied Chemsitry, Faculty of Engineering, Osaka City University
    • KATAYAMA Hiroyuki
    • Department of Applied Chemsitry, Faculty of Engineering, Osaka City University

抄録

The complexes <I>cis</I>-PtR(SiHPh<SUB>2</SUB>)(PMe<SUB>2</SUB>Ph)<SUB>2</SUB> (R = Me, Et, Pr, Bu) have been found to undergo two types of C–Si bond formation process. One is a novel reaction process <I>via</I> isomerization to <I>cis</I>-PtH(SiRPh<SUB>2</SUB>)(PMe<SUB>2</SUB>Ph)<SUB>2</SUB>, and the other is C–Si reductive elimination involving prior displacement of a PMe<SUB>2</SUB>Ph ligand with diphenylacetylene added to the system.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1289-1290, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004704037
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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