A New Process for C–Si Bond Formation from <i>cis</i>-Alkyl(silyl)platinum(II) Complexes
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- Fumiyuki Ozawa
- Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
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- Masaya Kitaguchi
- Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
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- Hiroyuki Katayama
- Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
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<jats:title>Abstract</jats:title> <jats:p>The complexes cis-PtR(SiHPh2)(PMe2Ph)2 (R = Me, Et, Pr, Bu) have been found to undergo two types of C–Si bond formation process. One is a novel reaction process via isomerization to cis-PtH(SiRPh2)(PMe2Ph)2, and the other is C–Si reductive elimination involving prior displacement of a PMe2Ph ligand with diphenylacetylene added to the system.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 28 (12), 1289-1290, 1999-12-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360565169063042944
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- NII論文ID
- 10004704037
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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