Insertion of Phenylacetylene into cis-Silyl(stannyl)platinum Complexes

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著者

    • OZAWA Fumiyuki
    • Department of Applied Chemistry, Faculty of Engineering, Osaka City University
    • SAKAMOTO Yasunobu
    • Department of Applied Chemistry, Faculty of Engineering, Osaka City University
    • SAGAWA Takashi
    • Department of Applied Chemistry, Faculty of Engineering, Osaka City University
    • TANAKA Rika
    • Department of Applied Chemistry, Faculty of Engineering, Osaka City University
    • KATAYAMA Hiroyuki
    • Department of Applied Chemistry, Faculty of Engineering, Osaka City University

抄録

Silyl(stannyl)platinum(II) complexes <I>cis</I>-Pt(SiR<SUB>3</SUB>)(SnMe<SUB>3</SUB>)(PMe<SUB>2</SUB>Ph)<SUB>2</SUB> (SiR<SUB>3</SUB> = SiMe<SUB>3</SUB>, SiMe<SUB>2</SUB>Ph, SiMePh<SUB>2</SUB>, SiPh<SUB>3</SUB>) undergo insertion of phenylacetylene into the Pt–Si or Pt–Sn bond. The site selectivity dramatically varies with silyl ligands under kinetic conditions, while under thermodynamic conditions the insertion into the Pt–Si bond exclusively takes place irrespective of silyl ligands.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1307-1308, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004704163
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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