The Fast Photochemical[2+2]Cycloaddition and Reverse Reaction of a Styrylpyrazine Amphiphile in Aqueous Dispersion

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著者

    • PARK Jong-mok
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • ZHANG Wanbin
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • NAKATSUJI Yohji
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • MAJIMA Tetsuro
    • The Institute of Scientific and Industrial Research, Osaka University
    • IKEDA Isao
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

Photochemical [2+2] cycloaddition of styrylpyrazine amphiphile <B>1</B> in aqueous dispersion occurred quantitatively and much faster than that of stilbene analogue <B>2</B>. Amphiphile <B>1</B> showed intermolecular photoreversible reactivity, [2+2] cycloaddition and the reverse reaction, in aqueous dispersion with alternate irradiation at above 300 and at 254 nm as the first example for 1,2-diarylethylene in aqueous dispersion.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1309-1310, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004704180
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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