Electrochemical Copolymerization of Bithiophene and Aniline in Aqueous-Organic Mixed Solution

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著者

    • HU Xiao
    • Advanced Materials Research Centre, School of Applied Science, Nanyang Technological University
    • WANG Guang-Ming
    • Advanced Materials Research Centre, School of Applied Science, Nanyang Technological University
    • NG Hanwah
    • Advanced Materials Research Centre, School of Applied Science, Nanyang Technological University
    • WONG Terrence K.S.
    • School of Electrical and Electronic Engineering, Nanyang Technological University

抄録

Polybithiophene (PBTh) and polyaniline (PAn) have been synthesized electrochemically in an aqueous-organic mixed solvent containing perchloric acid and acetonitrile. By using the mixed solvent system, the difference between the oxidation potentials of the two monomers is substantially reduced to 0.17 V from 0.55 V in pure acetonitrile organic medium. This enables the electrosynthesis of copolymer of bithiophene and aniline. Raman and absorption spectra were compared.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1999(12), 1323-1324, 1999-12-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004704275
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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