Recognition of Planar Chirality by Cyclodextrins

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著者

    • KANO Koji
    • Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University
    • TAKAOKA Ryoko
    • Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University
    • YAMAGUCHI Masahiko
    • Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University

抄録

Recognition of planar chirality of 14-hydroxy-12-oxabicyclo[9.2.2]pentadecane-1(14),11(15)-diene-1,13-dione (C8) and 16-hydroxy-14-oxabicyclo[11.2.2]heptadecane-1(16),13(17)-diene-2,15-dione (C10) by native and <I>O</I>-methylated cyclodextrins has been studied by NMR spectroscopy. The cyclodextrins prefer the (<I>R</I>)-enantiomers of C8 and C10, which might well fit with asymmetrically twisted cavities of cyclodextrins.

収録刊行物

  • Chemistry letters

    Chemistry letters 1999(12), 1337-1338, 1999-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10004704379
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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