Large Aliquot Injection Approach in the Electrothermal AAS Determination of Arsenic in Environmental Water Samples

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Determination of As by direct electrothermal atomization atomic absorption spectrometry with a pyropytically-coated graphite furnace treated with W by a single drop treatment technique was reported. The treated PG furnace made it possible to introduce a 100 µl aliquot of sample solution into the furnace with a high precision (RSD <4%). Use of a Pd-modifier made it possible to enhance the precision (RSD <3%) and the sensitivity. A good linearity (correlation factor >0.99) between integrated absorbance and injection volume was observed in the range 0 - 100 µl. The calculated detection limit and characteristic mass (sensitivity) for integrated absorbance were 22 ng l^-1 and 16 pg and for maximum absorbance were 45 ng l^-1 and 13 pg for a 100 µl injection with the Pd modifier at the optimum ashing temperature of 800°C. An interference study for environmental matrices was also carried out. The recoveries of 2 and/or 4 µg l^-1 of As added to various water samples, such as snow, cloud, river and tap waters, were 97 - 104%.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 16(2), 163-167, 2000-02-10

    Japan Society for Analytical Chemistry

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各種コード

  • NII論文ID(NAID)
    10004705151
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    5257412
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  IR 
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