Effective Desorption of Humic Substances from Amberlite XAD-2 Resin with Sodium Dodecyl Sulfate.

  • HIRAIDE Masataka
    Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University
  • UCHITOMI Kazutaka
    Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University

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抄録

The adsorption and desorption of humic and fulvic acids on a non-ionic macroreticular resin, Amberlite XAD-2, were studied from the view point of the concentration of aquatic humic substances. Microgram or milligram quantities of humic and fulvic acids were collected on a small column of pulverized XAD-2 (16 mm in diam.×5 mm height) and then desorbed with 10 cm3 of 0.1 mol dm-3 sodium hydroxide solution containing 200 mg of sodium dodecyl sulfate (SDS). The resulting humic solution contained appreciable amounts of SDS (ca. 100 mg), which were removed by introducing the solution onto another XAD-2 column (7 mm in diam.×60 mm height, unpulverized resin). The SDS was completely retained on the resin because of the strong affinity, even in an alkaline solution, whereas nearly all humic substances were passed through the column. The validity of the proposed separation method was evaluated by using synthetic sample solutions.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 15 (11), 1051-1054, 1999

    社団法人 日本分析化学会

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