Voltammetric Behavior of Adriamycin and Its Determination at Ni Ion-Implanted Electrode.

• HU Jingbo

  Department of Chemistry, Beijing Normal University

• LI Qilong

  Department of Chemistry, Beijing Normal University

抄録

With a Ni ion-implanted glassy carbon electrode (GCE) as the working electrode in 0.1 mol/l HAc-NaAc (pH=4.62) solution, a sensitive reductive wave of adriamycin was obtained by linear-sweep voltammetry. The peak potential was -0.55 V (vs. SCE). The peak current was proportional to the concentration of adriamycin over the range of 5.2×10^-7 - 1.0×10^-5 mol/l and the detection limit was 2.7×10^-7 mol/l. The behavior of the reduction wave was studied and the wave was applied to the determination of adriamycin in urine. The reduction process was quasi-reversible. AES and XPS experiments showed that Ni was surely implanted into the surface of the GCE, and the implanted Ni at the GCE improved the electrocatalytic activity.

収録刊行物

• Analytical Sciences

  Analytical Sciences 15 (12), 1215-1218, 1999

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390001204255795712
• NII論文ID: 130004440021
• NII論文ID: 10004708693
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.15.1215
• COI: 1:CAS:528:DyaK1MXotFSktbs%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 4952753
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4952753
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.15.1215.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.15.1215/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/15/12/15_12_1215/_pdf
• 本文言語コード: en
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