電解法による金属C_<60>ポリマーの合成 Synthesis of Metal C_<60> Polymer by Electrosis

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We tried to synthesize a new class of MC60 compounds with M=Rb, Sr and Y by an electrolysis process from solution. Two kinds of solution, 1.5mmol/l-C60 Toluene and 0.1mol/l-M(ClO4)x (x=1, M=Rb; x=2, M=Sr; x=3, M=Y) N, N-Dimethylformamide, were filled in the cathode cell and the anode cell, respectively. An ion exchange membrane separated the solution. Electrochemical properties were measured for the electrolyte solution. A black film was deposited on a silver cathode plate after the electrolysis. Raman spectra revealed that C60 molecules existed and were polymerized in the films. Characteristic shape of particles were observed in the obtained film. The coexistence of both C60 and metal was confirmed in the particles by an energy dispersive x-ray spectrometer. The film was crystallized after a post annealing at 160°C in a vacuum. The film slowly cooled after the annealing had a polymeric body-centered orthorhombic M1C60 phase, while the rapidly cooled film revealed a face centered cubic phase. The polymeric Sr1C60 and YIC60 were new materials obtained in this work, though the polymeric Rb1C60 has been well known.

収録刊行物

  • 電気学会論文誌. E, センサ・マイクロマシン準部門誌 = The transactions of the Institute of Electrical Engineers of Japan. A publication of Sensors and Micromachines Society  

    電気学会論文誌. E, センサ・マイクロマシン準部門誌 = The transactions of the Institute of Electrical Engineers of Japan. A publication of Sensors and Micromachines Society 118(7), 3552-357, 1998-07-01 

    The Institute of Electrical Engineers of Japan

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各種コード

  • NII論文ID(NAID)
    10004833604
  • NII書誌ID(NCID)
    AN1052634X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    13418939
  • NDL 記事登録ID
    4496662
  • NDL 雑誌分類
    ZN31(科学技術--電気工学・電気機械工業)
  • NDL 請求記号
    Z16-B380
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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