Retardation of the Molecular Rotation of p-Nitrophenolate Ion in the Cavity of a Positively Charged Derivative of α-Cyclodextrin by Electrostatic Interactions

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著者

    • AHMED Jalaluddin
    • Department of Life Science and Biotechnology, Faculty of Life and Environmental Science, Shimane University
    • NAGATA Takuya
    • Department of Life Science and Biotechnology, Faculty of Life and Environmental Science, Shimane University
    • IMAOKA Shinji
    • Department of Life Science and Biotechnology, Faculty of Life and Environmental Science, Shimane University
    • MATSUI Yoshihisa
    • Department of Life Science and Biotechnology, Faculty of Life and Environmental Science, Shimane University
    • YAMAMOTO Tatsuyuki
    • Department of Life Science and Biotechnology, Faculty of Life and Environmental Science, Shimane University

抄録

<SUP>1</SUP>H NMR signal for the C(5)-H of A, D glucose residues of bis[6<SUP>A</SUP>,6<SUP>D</SUP>-(1-pyridinio)-6<SUP>A</SUP>,6<SUP>D</SUP>-deoxy]-α-cyclodextrin shifted downfield, whereas those of B, E and C, F residues shifted upfield, with the addition of <I>p</I>-nitrophenol at pD 11.3. This infers that the molecular rotation of the guest is retarded in the CD cavity.

収録刊行物

  • Chemistry letters

    Chemistry letters 2000(8), 960-961, 2000-08-05

    The Chemical Society of Japan

参考文献:  9件中 1-9件 を表示

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各種コード

  • NII論文ID(NAID)
    10004954310
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    OTR
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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