Electrochemical Characteristic of 2-Mercaptobenzothiazole Self-Assembled Monolayer on Gold

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Abstract

A monolayer membrane of 2-mercaptobenzothiazole (MBT) was prepared on a gold electrode through a self-assemblyprocedure. The monolayer structure and the electrochemical properties were investigated by various electrochemicaltechniques, like cyclic voltammetry and an impedance measurement with external redox. Experiments show that MBTcan form a closely packed monolayer that can be charged due to the active N atom. The amount of charge on themembrane surface varies with the solution pH, and the monolayer shows “opening and closing” which depends on thesolution pH. The electrostatic interaction of the monolayer with other ions is also related to the pH in solution. Animpedance analysis shows that the heterogeneous electron-transfer rate of a fast redox like Fe(CN)63-/4- decreases from 1.2 × 10-2 to 4.7 × 10-5 cm s-1 in neutral solution due to blockage of the self-assembled monolayer membrane.

Journal

  • Analytical Sciences

    Analytical Sciences 16 (5), 457-461, 2000

    The Japan Society for Analytical Chemistry

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