機能性高度不飽和脂質の調製と酸化防止

DOI Web Site Web Site 被引用文献2件 参考文献77件

書誌事項

タイトル別名
  • Preparation and Oxidation Prevention of Functional Polyunsaturated Lipids
  • ヘイセイ 11ネンド ニホン ユカガクカイ ガッカイショウ キノウセイ コウド フホウワ シシツ ノ チョウセイ ト サンカ ボウシ

この論文をさがす

抄録

The paper is based on the article that qualified for the 1999 Japan Oil Chemists' Society Award. Novel methods for obtaining triacylglycerols (PUFA-TG) and glycerophospholipids (PUFA-PL) having functional polyunsaturated fatty acids such as docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA) are first reviewed. Physiologically beneficial PUFA-TG with 90% PUFA was prepared through triplicate transacylation of tuna orbital oil with PUFA at 60°C for 7.5h with immobilized lipase from Rhizomucor miehei in combination with ethyleneglycol or propyleneglycol as alternatives for essential water indispensable for enzyme activation. PL with 38% PUFA content was prepared with 83% recovery by 4 repeated transacylations of soy PL with polyunsaturated monoacylglycerol (PUFA-MG) using microbial lipase from Candida cylindracea. PUFA-MG could be used in place of essential water for inducing enzyme activity and also as a polyunsaturated acyl donor.<BR>Study was made of the antioxidative and synergistic effects of amino compounds for autoxidation of PUFA-TG. Amino compounds such as nitrogen-containing PLs, alkylamines and spermine were found to possess but little antioxidative activity compared to the tocopherol mixture. The remarkable synergistic activity of primary amino group toward tocopherols was detected in the autoxidation of PUFA-TG in non-aqueous or emulsifying systems. Primary amino hydrogen in amino compounds may possibly function quite well as hydrogen radical donors for regenerating tocopherols.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 48 (11), 1233-1245,1319, 1999

    公益社団法人 日本油化学会

被引用文献 (2)*注記

もっと見る

参考文献 (77)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ