Facile Formation and Dissociation Behaviour of C-C Bond Resulted from the Nucleophilic Attack of Carbanions on a Carbonyl Carbon in [Pt(hfac)2]

• Okeya, Seichi

• Hashimoto, Masato

• Nakamura, Fumiko

• Kusuyama, Yoshiaki

• Kobayashi, Mako

• Arakawa, Ryuichi

抄録

[Pt(hfac)2] (hfac:hexafluoroacetylacetonate) reacts with MeNH2 in CH2Cl2/MeOH to give an –NHMe adduct complex on one of the carbonyl carbons, (MeNH3)[Pt(hfac)(hfac–NHMe)] 1 which is a tetrahedral intermediate of a Schiff base complex,[Pt(CF3COCHC(NMe)CF3)2] 2. Complex 1 activates H2O,MeOH, MeNO2 or acetone in solution to form the corresponding conjugate base adducts. The C–C bond in–CH2NO2 adduct 6, easily cleaves and generates nitromethane in solution.

収録刊行物

• Chemistry Letters

  Chemistry Letters 29 (10), 1130-1131, 2000-07-07

  The Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1050282677887831296
• NII論文ID: 10006222582
• NII書誌ID: AA00603318
• ISSN: 03667022
• ISSN: 13480715
• DOI: 10.1246/cl.2000.1130
• HANDLE: 10112/5939
• Web Site: https://kansai-u.repo.nii.ac.jp/records/11490
• Web Site: https://academic.oup.com/chemlett/article-pdf/29/10/1130/56078584/cl.2000.1130.pdf
• 本文言語コード: en
• 資料種別: journal article
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