Nano-Phase Separation in the Monolayer Composed of α-Helical Copolypeptide at Air/Water Interface

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  • Hidenori Yokoi
    Department of Materials Science and Engineering, Nagoya Institute of Technology
  • Takatoshi Kinoshita
    Department of Materials Science and Engineering, Nagoya Institute of Technology
  • Yoshiharu Tsujita
    Department of Materials Science and Engineering, Nagoya Institute of Technology
  • Hiroaki Yoshimizu
    Department of Materials Science and Engineering, Nagoya Institute of Technology

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<jats:title>Abstract</jats:title> <jats:p>Nanometer-scale stripe pattern in the monolayer composed of α-helical copolypeptide was characterized with atomic force microscope (AFM). This monolayer was formed with the copolypeptide composed of poly(ε-benzyloxycarbonyl l-lysine)x-poly[(γ-methyl l-glutamate)y-z/(l-glutamic acid)z] (PLLZx–P(MLGy-z/LGAz)). AFM image of Langmuir–Blodgett (LB) film of this copolypeptide showed a nanometer-scale stripe pattern. This pattern seems to be based on the nanophase-separated structure in the copolypeptide monolayer at air/water interface.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 29 (10), 1210-1211, 2000-10-01

    Oxford University Press (OUP)

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