Preparation of SiC Dispersed Fe0.98Co0.02Si2 by Pressureless Sintering with Cu and Si Addition and Its Thermoelectric Performance
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- Ito Mikio
- Department of Materials Science and Processing, Graduate School of Engineering, Osaka University
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- Nagai Hiroshi
- Department of Materials Science and Processing, Graduate School of Engineering, Osaka University
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- Katsura Takayuki
- Department of Materials Science and Processing, Graduate School of Engineering, Osaka University
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- Katsuyama Shigeru
- Department of Materials Science and Processing, Graduate School of Engineering, Osaka University
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- Majima Kazuhiko
- Department of Materials Science and Processing, Graduate School of Engineering, Osaka University
書誌事項
- タイトル別名
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- Preparation of SiC Dispersed Fe<SUB>0.98</SUB>Co<SUB>0.02</SUB>Si<SUB>2</SUB> by Pressureless Sintering with Cu and Si Addition and Its Thermoelectric Performance
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The SiC-dispersed β–FeSi2 compounds were synthesized by pressureless sintering with Cu and Si addition without a subsequent heat treatment for β phase formation. The effects of Cu and Si addition on the phase transformation, sintering behavior, and thermoelectric performance of these samples were investigated. Cu addition significantly accelerated the β phase formation during the pressureless sintering, and the samples with Cu were mostly composed of the β phase with a small amount of the residual α and ε phases. Cu addition was effective for densification; Cu–Si liquid phase formation resulted in a high relative density of over 90%. The thermoelectric power and thermal conductivity of the pressurelessly sintered samples with Cu addition were quite lower and higher, respectively, than those of the hot-pressed sample. The differences were caused by a larger amount of metallic phases, such as the ε and Cu–Si phases. The figure of merit of these samples was about 1/3 of that of the hot-pressed sample, indicating that Cu addition completely ruined the enhancement of thermoelectric performance obtained by SiC dispersion. The addition of Si to the samples with Cu decreased the amount of the metallic ε phase and increased the amount of the semiconducting β phase through the reaction ε+Si→β. The thermoelectric power and thermal conductivity of the samples with Cu were markedly improved by Si addition, which resulted in a significant increase in the figure of merit. The values of the figure of merit for the samples with Cu and Si addition were almost the same as that of the hot-pressed sample with SiC dispersion.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 42 (7), 1451-1457, 2001
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390001204248439040
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- NII論文ID
- 130004451590
- 10006551251
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- NII書誌ID
- AA1151294X
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- COI
- 1:CAS:528:DC%2BD3MXmsFyrtrg%3D
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 5889935
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可