Determining the phase transition of condensate formed by heterogeneous nucleation of condensable vapors onto a cold substrate.
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- Shinagawa Hideo
- Department of Chemical Engineering, Hiroshima University
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- Miyamoto Ken-ichi
- Department of Chemical Engineering, Hiroshima University
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- Hamada Takuya
- Department of Chemical Engineering, Hiroshima University
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- Okuyama Kikuo
- Department of Chemical Engineering, Hiroshima University
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- Wyslouzil Barbara Ellen
- Department of Chemical Engineering, Worcester Polytechnic Institute
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抄録
The heterogeneous phase transition of four organic vapors and water vapor on a cold substrate was studied by either slowly cooling a substrate or by accumulating vapor under reduced-pressure conditions. At low vapor pressures a solid condensate formed directly on the substrate. At higher vapor pressures, liquid condensate usually appeared first, followed either by1) subsequent formation of solid crystals independently from the liquid phase (subsequent solidification) or 2) rapid freezing of the liquid condensate (subsequent freezing). Subsequent freezing occurred in a wider temperature range than did the subsequent solidification. A new phase transition model is proposed, based on the equilibrium phase diagram and the measured relationship between critical vapor pressure and temperature for solid condensate formation. The proposed model explains the experimental results quite well. Liquid condensate always forms at critical supersaturation ratios close to unity. The critical vapor pressure and temperature at the boundary separating the formation of the solid condensate from formation of the liquid condensate, as determined by the proposed model, agrees well with the experimentally determined values.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 27 (3), 284-290, 1994
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204566209792
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- NII論文ID
- 10006959611
- 10003026578
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DyaK2cXks1SnsLw%3D
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- ISSN
- 18811299
- 00219592
- http://id.crossref.org/issn/00219592
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可