Effect of Pressure on the Alcoholysis of Triacylglycerol.

• TAGUCHI Yoichi

  National Institute of Advanced Industrial Science and Technology (AIST)

• BALETA Angelo S.

  Industrial Technology Development Institute

• MANONGSONG Evelyn B.

  Industrial Technology Development Institute

• OISHI Akihiro

  National Institute of Advanced Industrial Science and Technology (AIST)

• FUJITA Ken-ichi

  National Institute of Advanced Industrial Science and Technology (AIST)

抄録

The pressure effect of alcoholysis of triacylglycerol was studied in the absence of a catalyst. The methanolysis of trilauroylglycerol was accelerated greatly by compression when the solvents that include chlorines in a molecule were used. There was no significant difference in the pressure effect among the three steps of which the methanolysis of trilauroylglycerol composed. The order of the pressure effect of alcohol on the alcoholysis of trilauroylglycerol was methyl alcohol>other primary alcohol>secondary alcohol>tertiary alcohol. On the methanolysis in CH₂Cl₂, trioleoylglycerol was accelerated by pressure more than trilauroylglycerol, and trimilistoylglycerol and tripalmitoylglycerol had a similar pressure effect to trilauroylglycerol, whereas methanolysis of tristearoylglycerol had a peculiar pressure effect.

収録刊行物

• Journal of Oleo Science

  Journal of Oleo Science 50 (12), 951-956, 2001

  公益社団法人 日本油化学会

キーワード

• high-pressure
• pressure effect
• methanolysis
• alcoholysis
• triacylglycerol
• trilauroylglycerol
• tristearoylglycerol
• no catalyst

詳細情報

• CRID: 1390001204091046528
• NII論文ID: 10007267686
• NII書誌ID: AA11503337
• DOI: 10.5650/jos.50.951
• COI: 1:CAS:528:DC%2BD3MXosleru7g%3D
• ISSN: 13473352
• ISSN: 13458957
• NDL書誌ID: 5995562
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5995562
• Web Site: https://www.jstage.jst.go.jp/article/jos/50/12/50_12_951/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可