熱誘起相分離法による多孔膜の作製と微細構造制御 Structure Control of Porous Membrane Prepared by Thermally Induced Phase Separation

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著者

    • 松山 秀人 MATSUYAMA Hideto
    • 京都工芸繊維大学工芸学部物質工学科 Department of Chemistry and Materials Technology, Kyoto Institute of Technology

抄録

The thermally induced phase separation (TIPS) process is a valuable way of making microporous materials, such as membranes and foams. TIPS process consists of the following steps.<BR>1. A homogeneous solution is formed at an elevated temperature by blending the polymer with a high-boiling, low molecular weight liquid (diluent).<BR>2. The solution is formed into the desired shape (flat sheet, tube, hollow fiber).<BR>3. The solution is cooled at a controlled rate or quenched to induce phase separation.<BR>4. The diluent is removed typically by solvent extraction.<BR>5. The extracatnt is removed typically by evaporation to produce a microporous structure.<BR>This paper mainly focuses on the kinetics of phase separation in the TIPS process. The studies on phase separation by the light scattering method, kinetics of droplet growth in the latter stage of phase separation and the computer simulation on dynamics of spinodal decomposition are reviewed briefly. Accurate engineering of the TIPS process is essential for control of microstructural properties such as pore size, pore size distribution and porosity, since these properties ultimately determine the performance of the microporous membranes.

収録刊行物

  • 膜 26(3), 116-123, 2001-05-01

    THE MEMBRANE SOCIETY OF JAPAN

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各種コード

  • NII論文ID(NAID)
    10008010478
  • NII書誌ID(NCID)
    AN0023215X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    03851036
  • NDL 記事登録ID
    5788462
  • NDL 雑誌分類
    ZR2(科学技術--生物学--生化学)
  • NDL 請求記号
    Z18-1127
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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