無機マイクロポーラス膜の微細構造制御と透過性能 Permeation properties and microstructure of porous inorganic membranes

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Microstructures of porous inorganic membranes and permeation properties through those membranes were reviewed for amorphous silica membranes and zeolite membranes. Silica membranes were compared by the permeation properties of hydrogen such as activation energies or selectivities over nitrogen or helium. The activation energies of hydrogen through silica membranes prepared by the sol-gel method and the CVD method were the same level, and relatively loose or dense structure can be made by both methods. The effects of intercrystalline pathways on the permeation properties through zeolitic membranes were investigated. The intercrystalline pathways were filled by coking of a hydrocarbon or counterdiffusion CVD method. The permeation properties through intercrystalline pathways were explained by an i-i model. According to this model, ethanol was permselective from ethanol aqueous solution through intercrystalline pathways of the MFI zeolite membrane.

収録刊行物

  • 膜 26(3), 124-133, 2001-05-01

    THE MEMBRANE SOCIETY OF JAPAN

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各種コード

  • NII論文ID(NAID)
    10008010520
  • NII書誌ID(NCID)
    AN0023215X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    03851036
  • NDL 記事登録ID
    5788476
  • NDL 雑誌分類
    ZR2(科学技術--生物学--生化学)
  • NDL 請求記号
    Z18-1127
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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