Measurement of Solubility of Oxygen in Electrolyte Solution Used in Salt Manufacturing Process

• OHKUBO Kazuya

  Sea Water Science Research Laboratory, The Salt Industry Center of Japan

Bibliographic Information

Other Title

• 製塩工程における高濃度電解質水溶液の溶存酸素濃度測定
• セイエン コウテイ ニ オケル コウノウド デンカイシツ スイヨウエキ ノ ヨウゾン サンソ ノウド ソクテイ

Abstract

The determination of dissolved oxygen using the Winkler method in an electrolyte solution such as brine or mother liquid used in a salt manufacturing process is discussed. The solubility of oxygen in pure water at 298-363 K conforms to the value proposed by Winkler. And the measured values of brine obtained from salt farms using the Winkler method and the van Slyke-Neil method are almost the same. It is believed that the Winkler method is effective for measuring the solubility of dissolved oxygen at high temperatures.<BR>On the other hand, the salting-out parameters of oxygen are calculated using the relationship between the solubility of oxygen and the ionic strength in NaCl, MgCl₂, CaCl₂, KCl solutions, respectively. The solubility of oxygen in various mixed electrolyte solutions is accurately estimated by using the salting-out parameters and the ionic strength at 343 and 363 K. From these results, it is believed that the solubility of oxygen can be calculated from the composition of electrolyte solution.

Journal

• Bulletin of the Society of Sea Water Science, Japan

  Bulletin of the Society of Sea Water Science, Japan 54 (2), 111-116, 2000

  The Society of Sea Water Science, Japan

Details

• CRID: 1390282680429590912
• NII Article ID: 10008275709
• NII Book ID: AN0018645X
• DOI: 10.11457/swsj1965.54.111
• COI: 1:CAS:528:DC%2BD3cXitleit7s%3D
• NDL BIB ID: 5334511
• ISSN: 03694550
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5334511
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • CiNii Articles
  • Crossref
• Abstract License Flag: Disallowed