Effect of Chlorine on Direct Photodegradation of Phosgene in Gaseous Phase
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- YAMAMOTO Shin
- Graduate School of Environment and Information Sciences, Yokohama National University
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- ITOH Kiminori
- Graduate School of Environment and Information Sciences, Yokohama National University
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- MURABAYASHI Masayuki
- Graduate School of Environment and Information Sciences, Yokohama National University
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Abstract
<p>The effect of Cl radical on direct photodegradation rates of phosgene was investigated using the circulation-type apparatus. Cl radical was hardly formed from molecular chlorine using a low-pressure mercury lamp, which had been employed for direct photodegradation of phosgene, because the spectrum of low-pressure mercury lamp is hardly absorbed by molecular chlorine. It was observed that Cl radical was formed from molecular chlorine by the irradiation from black-lights. Under presence of molecular chlorine and the irradiation from black-lights, significant increase in the rate constant of photodegradation of phosgene using low-pressure mercury lamp was observed. In addition small effect of increase of residence time in the reactor was observed.</p>
Journal
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- Electrochemistry
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Electrochemistry 70 (6), 425-428, 2002-06-05
The Electrochemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390845702278138368
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- NII Article ID
- 10008573487
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- NII Book ID
- AN00151637
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- ISSN
- 21862451
- 13443542
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- NDL BIB ID
- 6179948
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Allowed