Solid-solid Photocatalytic Reaction of Malonic Acid. Allowed Limit Amount of H<sub>2</sub>O to Give Characteristic Product Selectivity
-
- HARADA Hisashi
- Department of Chemistry, Meisei University, and Advanced Material Research and Development Center, Meisei University
-
- SUDA Koji
- Department of Chemistry, Meisei University, and Advanced Material Research and Development Center, Meisei University
Bibliographic Information
- Other Title
-
- Solid-solid Photocatalytic Reaction of Malonic Acid. Allowed Limit Amount of H2O to Give Characteristic Product Selectivity
Search this article
Abstract
<p>This paper deals with solid-solid photocatalysis; i.e. photocatalytic reaction for a solid substrate using Pt/TiO2 powdered photocatalyst (solid) under illumination. Malonic acid reacts to CO2 and a small amount of other minor products in an aqueous suspension of powdered photocatalyst under Ar atmosphere. In the case of the solid-solid system, CH4 was also produced from malonic acid as a major product together with CO2. The change of products distribution was observed and the changing behavior of products distribution with an addition of water was examined. Our result showed that the allowed limit amount of water to change the selectivity could be determined. Scheme of product switching was also discussed.</p>
Journal
-
- Electrochemistry
-
Electrochemistry 70 (6), 435-437, 2002-06-05
The Electrochemical Society of Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390282752324853760
-
- NII Article ID
- 10008573527
-
- NII Book ID
- AN00151637
-
- ISSN
- 21862451
- 13443542
-
- NDL BIB ID
- 6180016
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Allowed