Photophysical and Electrochemical Properties of Novel Symmetrical and Unsymmetrical 1,4,5,8-naphthalenetetracarboxydiimide Derivatives

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A series of symmetrical and unsymmetrical 1,4,5,8-naphthalenetetracarboxydiimide (NDIM) derivatives were characterized by UV-visible and fluorescence spectral analyses in order to understand the relationships between their structures and physical properties. The UV-visible spectral analyses showed the intermolecular interactions on phenyl group of 3,3-diphenylpropyl derivatives, and the fluorescence spectra suggested the weak intermolecular interactions for 2,5-di-tert-butylphenyl derivatives. These results revealed that 3,5-di-tert-butylphenyl group is one of the best substituents for disturbing the intermolecular interaction. The redox potentials of reduction for NDIM derivatives were slightly shifted to the negative region by the introduction of electron-donating substituents.

収録刊行物

  • Journal of oleo science

    Journal of oleo science 51(6), 427-432, 2002-06-01

    Japan Oil Chemists' Society

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各種コード

  • NII論文ID(NAID)
    10008574273
  • NII書誌ID(NCID)
    AA11503337
  • 本文言語コード
    ENG
  • 資料種別
    NOT
  • ISSN
    13473352
  • NDL 記事登録ID
    6261935
  • NDL 雑誌分類
    ZP25(科学技術--化学・化学工業--油脂類)
  • NDL 請求記号
    Z54-J571
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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