直接メタノール燃料電池用電解質膜の現状と新展開 Present State and Novel Development of Polymer Electrolyte Membranes for Direct Methanol Fuel Cell

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著者

    • 山口 猛央 YAMAGUCHI Takeo
    • 東京大学大学院工学系研究科 化学システム工学専攻 Department of Chemical System Engineering, The University of Tokyo

抄録

To develop a high performance direct methanol fuel cell (DMFC), a novel electrolyte membrane is needed. This electrolyte membrane should be durable up to 130t to improve the catalytic reaction, and the methanol crossover should be reduced. Reported membranes are reviewed in this article, and our own approach is shown. Our approach is to design a pore-filling type polyelectrolyte membrane, where the polyelectrolyte is filled into the pores of a porous substrate, and the membrane swelling is suppressed by the substrate matrix. Proton conductivity was achieved through the filling electrolyte polymer. Methanol permeation was controlled by the swelling of the electrolyte polymer, and the mechanical strength at high temperature was maintained by the substrate. From this concept, a high proton conductivity was shown to exist with reduced membrane methanol permeability, and in addition, a heat-resistance was also achieved.

収録刊行物

  • 膜 27(3), 124-130, 2002-05-01

    THE MEMBRANE SOCIETY OF JAPAN

参考文献:  21件中 1-21件 を表示

  • <no title>

    WATANABE M.

    J. Electrochem, Soc 143, 3847, 1996

    被引用文献8件

  • <no title>

    YANG C.

    Electrochem. Solid State Lett. 4, A31, 2000

    被引用文献1件

  • <no title>

    渡利竜也

    化学工学会年会要旨集 N104, 2002

    被引用文献1件

  • <no title>

    WAINRIGHT J. S.

    J. Electrochem. Soc 142, L121, 1995

    被引用文献15件

  • <no title>

    PARK Y. -I.

    J. Electrochem. Soc. 148, A616, 2001

    被引用文献2件

  • <no title>

    LEHTINEN T.

    Electrochim. Acta 43, 1881, 1998

    被引用文献2件

  • <no title>

    LEE W.

    J. Electrochem. Soc. 143, 2795, 1996

    被引用文献3件

  • <no title>

    YAMAGUCHI T.

    Macromolecules 24, 5522, 1991

    被引用文献8件

  • <no title>

    YAMAGUCHI T.

    Ind. Eng. Chem. Res. 31, 1914, 1992

    被引用文献8件

  • <no title>

    YAMAGUCHI T.

    J. Membrane Sci. 194, 217, 2001

    被引用文献3件

  • <no title>

    YAMAGUCHI T.

    Ind. Eng. Chem. Res. 37, 177, 1998

    被引用文献2件

  • <no title>

    WANG B-G

    J. Membrane Sci. 164, 25, 2000

    被引用文献3件

  • <no title>

    WANG B. -G.

    Polymer 42, 5225, 2001

    被引用文献2件

  • <no title>

    林英樹

    第48回高分子討論会要旨集 IIb050, 1999

    被引用文献1件

  • <no title>

    宮田房枝

    化学工学会年会要旨集 N103, 2002

    被引用文献1件

  • <no title>

    ZAWODZINSKI

    Solid State Ionics 60, 199, 1993

    DOI 被引用文献5件

  • <no title>

    BARADIE B.

    J. Electroanal. Chem. 489, 101, 2000

    DOI 被引用文献2件

  • <no title>

    MIYAKE N.

    J. Electrochem. Soc. 148, A905, 2001

    被引用文献6件

  • <no title>

    RIKUKAWA M.

    Prog. Polym. Sci. 25, 1463, 2000

    DOI 被引用文献9件

  • <no title>

    HONMA I.

    Solid State Ionics 120, 255, 1999

    DOI 被引用文献7件

  • <no title>

    DEPRE L.

    Electrochim. Acta 45, 1377, 2000

    DOI 被引用文献4件

被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10008588870
  • NII書誌ID(NCID)
    AN0023215X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    03851036
  • NDL 記事登録ID
    6152310
  • NDL 雑誌分類
    ZR2(科学技術--生物学--生化学)
  • NDL 請求記号
    Z18-1127
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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