新しいプロトン伝導高分子電解質膜 Novel Proton Conducting Polymer Electrolyte Membranes

この論文にアクセスする

この論文をさがす

著者

抄録

This article reviews recent progress in the proton conducting polymer electrolyte membranes for fuel cell applications. Functionalization of aromatic hydrocarbon polymers such as poly ether ether ketone (PEEK), polysulfone (PSF), polyphenylene sulfide (PPS), polyimide (PI), polybenzimidazole (PBI), polyphosphazene, and fluorinated polystyrene is described. The approaches include direct sulfonation, polymerization of functionalized monomers, sulfo-and phosphoalkylation, and acid/base complexation. High proton conductivity, (up to 0.3 Scm<SUP>-1</SUP> at RH 100% and 20°C) has been obtained for these polymer electrolyte membranes. Since hydrophobic/hydrophilic separation for hydrocarbon polymer electrolytes is less pronounced than that of perfluorinated ionomer, acid functional groups should be placed closely each other and apart from the hydrophobic segments for high proton conductivity as well as oxidative and hydrolytic stability. Proton conduction under nonaqueous conditions (without humidification) is also proposed for sulfonated PPS/oligo (ethylene oxide) composite and polyhydroxylated fullerene.

収録刊行物

  • 膜 27(3), 131-138, 2002-05-01

    THE MEMBRANE SOCIETY OF JAPAN

参考文献:  35件中 1-35件 を表示

  • <no title>

    STECK AE.

    Proceedings of the "First International Symposium on New Materials for Fuel Cell Systems" Montreal 74, 1995

    被引用文献1件

  • <no title>

    WAINRIGHT J. S.

    J. Electrochem. Soc 142, L121, 1995

    被引用文献15件

  • <no title>

    田村正之

    特開平6-231779, 1994

    被引用文献1件

  • <no title>

    HOBSON LJ.

    J. Electrochem. Soc. 148, A1185, 2001

    被引用文献1件

  • <no title>

    WATANABE M.

    J.Phys.Chem. 102, 3129, 1998

    被引用文献2件

  • <no title>

    DOYLE M.

    J. Electrochem. Soc. 147, 34, 2000

    被引用文献15件

  • <no title>

    KREUER KD.

    J. Membr. Sci. 185, 29, 2001

    被引用文献1件

  • <no title>

    WANG F.

    Macromol. Symp. 175, 387, 2001

    被引用文献1件

  • <no title>

    HUBNER G.

    J. Mater. Chem. 9, 409, 1999

    被引用文献2件

  • <no title>

    MIYATAKE K.

    J. Polym. Sci. A: Polym. Chem. 39, 3211, 2001

    被引用文献1件

  • <no title>

    MIYATAKE K.

    J. Polym. Sci. A: Polym. Chem. 39, 3770, 2001

    被引用文献1件

  • <no title>

    TSUCHIDA E.

    Angew. Chem. Int. Ed. Engl. 35, 2843, 1996

    被引用文献5件

  • <no title>

    MIYATAKE K.

    Macromolecules 29, 6969, 1996

    被引用文献5件

  • <no title>

    MIYATAKE K.

    Macromolecules 30, 2941, 1997

    被引用文献5件

  • <no title>

    MIYATAKE K.

    Chem.Mater. 11, 1171, 1999

    被引用文献5件

  • <no title>

    宮武健治

    電気化学会第69回大会予稿集 92, 2002

    被引用文献1件

  • <no title>

    GIESELMAN MB.

    Macromolecules 25, 4832, 1992

    被引用文献1件

  • <no title>

    別所啓一

    特開平9-87510, 1994

    被引用文献1件

  • <no title>

    KAWAHARA M.

    Polym. Adv. Tech. 11, 544, 2000

    被引用文献1件

  • <no title>

    JONES DJ.

    J. Membr. Sci. 185, 41, 2001

    被引用文献1件

  • <no title>

    WAINRIGHT JS.

    Proc. Electrochem. Soc. 94, 255, 1994

    被引用文献1件

  • <no title>

    GUO Q.

    J. Membr. Sci. 154, 175, 1999

    被引用文献2件

  • <no title>

    WEI J.

    US Patent 5422411, 1995

    被引用文献1件

  • <no title>

    BEATTIE PD.

    J. Electroanal. Chem. 503, 45, 2001

    被引用文献1件

  • <no title>

    STECK AE.

    Proceedings of the "Second International Symposium on New Materials for Fuel Cell and Modern Battery Systems" Montreal 792, 1997

    被引用文献1件

  • <no title>

    STONE C.

    J. New Mater. Electrochem. Systems 3, 43, 2000

    被引用文献2件

  • <no title>

    CHIANG L. Y.

    J. Org. Chem. 59, 3960, 1994

    被引用文献3件

  • <no title>

    GRONDIN J.

    Solid State Ionics 77, 70, 1995

    DOI 被引用文献1件

  • <no title>

    ZUKOWSKA C.

    Chem. Mater. 12, 3578, 2000

    DOI 被引用文献1件

  • <no title>

    HONMA I.

    Solid State Ionics 120, 255, 1999

    DOI 被引用文献7件

  • <no title>

    MIYATAKE K.

    Macromolecules 34, 2065, 2001

    DOI 被引用文献2件

  • Soluble Sulfonated Naphthalenic Polyimides as Materials for Proton Exchange Membranes

    GENIES C.

    Polymer 42, 359-373, 2001

    DOI 被引用文献4件

  • <no title>

    RIKUKAWA M.

    Prog. Polym. Sci. 25, 1463, 2000

    DOI 被引用文献9件

  • <no title>

    WYCISK R.

    J. Membr. Sci. 119, 155, 1996

    DOI 被引用文献2件

  • <no title>

    HINOKUMA K.

    Chem. Phys. Lett. 341, 442, 2001

    DOI 被引用文献10件

被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10008588892
  • NII書誌ID(NCID)
    AN0023215X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    03851036
  • NDL 記事登録ID
    6152319
  • NDL 雑誌分類
    ZR2(科学技術--生物学--生化学)
  • NDL 請求記号
    Z18-1127
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
ページトップへ