Generation and Detection of a Dithia Dication Derived from 4,9-Diethyl-[1,4]dihydrodithiino[5,6-f]benzotrithiole 5-Oxide and Its Disproportionation

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著者

    • ITO Shinya
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • SASAKI Takashi
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • OGAWA Satoshi
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • SATO Ryu
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University

抄録

A dithia dication was generated from 4,9-diethyl[1,4]-dihydrodithiino[5,6-<I>f</I>]benzotrithiole 5-oxide on treatment with D<SUB>2</SUB>SO<SUB>4</SUB>. Hydrolysis of the dication gave 4,9-diethyl[1,4]dihydrodithiino[5,6-<I>f</I>]benzotrithiole 1-oxide and 2-oxide, suggesting that the positive charges, generated on the dithiin ring, transferred to the trithiole ring. A disproportionation of the dithia dication was observed in the solution.

収録刊行物

  • Chemistry letters

    Chemistry letters 2002(5), 540-541, 2002-05-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008689233
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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