その場観察・測定による酸化物結晶の成長機構解析 Analysis on Crystal Growth Mechanism of Oxides by In-situ Observation Method

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Growth mechanism of oxide crystals from a heterogeneous condition of solid-melt mixtures formed by incongruent melting has been analyzed using a newly developed in-situ observation system, which is composed of a time-resolving X-ray powder diffraction apparatus using a PSPC (Position Sensitive Proportional Counter) combined with an optical microscope, images of which are detected by a CCD sensor and stored into a video-recording system. Measurements are carried out on the oxide superconductor system Y-Ba-Cu-O, where well-habited single crystals of the superconductive compound YBa<SUB>2</SUB>Cu<SUB>3</SUB>O<SUB>x</SUB> are easily obtained from a mixture of solid Y<SUB>2</SUB>BaCuO<SUB>5</SUB> and liquid with the aid of the peritectic reaction. The results indicate that recrystallization by Ostwald ripening plays a main role in such a heterogeneous condition and diffusion of YBa<SUB>2</SUB>Cu<SUB>3</SUB>O<SUB>x</SUB> molecules in the liquid phase determines the whole growth rate.

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  • 鉱物学雜誌 = Journal of the Mineralogical Society of Japan

    鉱物学雜誌 = Journal of the Mineralogical Society of Japan 24(4), 253-258, 1995-10-01

    Japan Association of Mineralogical Sciences

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各種コード

  • NII論文ID(NAID)
    10008767631
  • NII書誌ID(NCID)
    AN00084868
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    04541146
  • NDL 記事登録ID
    4226725
  • NDL 雑誌分類
    ZM46(科学技術--地球科学--岩石・鉱物・鉱床)
  • NDL 請求記号
    Z15-117
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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