14族元素間σ結合の開裂を伴う錯体触媒反応と触媒活性種関連錯体の挙動 Transition Metal Catalysis Involving Cleavages of σ-Bonds between Group 14 Elements and Characterization of Metal Complexes Relevant to the Catalyst Intermediates

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Some homogeneous transition metal catalysts are highly active to cleave σ-bonds between group 14 elements under mild reaction conditions. Various unsaturated compounds insert into the a-bonds to afford a wide variety of products having the group 14 elements. We have utilized silylstannanes (Si-Sn), disilanes (Si-Si), and distannanes (Sn-Sn) in the presence of a transition metal catalyst to realize 1, 4-silylstannation of 1, 3-dienes, 1, 2-silylstannation of olefins, dimerization and bis-silylation of 1, 3-dienes, 1, 4-carbosilylation of 1, 3-dienes, silylation of allylic esters, and bisstannylation of 1, 3-dienes. The structures and fluxional behavior of <I>cis</I>-bis (stannyl) bis (phosphine) platinum, <I>cis</I>-bis (silyl) bis (phosphine) platinum, and <I>cis</I>-bis (stannyl) bis (phosphine) palladium complexes were examined. In the fluxional process, all the spin-spin couplings are retained. The fluxionality is attributed to unimolecular twist-rotation via a pseudotetrahedral transition state.

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  • 有機合成化学協会誌

    有機合成化学協会誌 58(3), 199-207, 2000-03-01

    The Society of Synthetic Organic Chemistry, Japan

参考文献:  51件中 1-51件 を表示

  • <no title>

    DAVIES A. G.

    Comprehensive Organometallic Chemistry II 2, 1995

    被引用文献1件

  • <no title>

    MITCHELL T. N.

    J. Chem. Soc., Chem. Commun. 1985, 354

    被引用文献4件

  • <no title>

    MITCHELL T. N.

    J.Org.Chem. 52, 4868, 1987

    被引用文献3件

  • <no title>

    CHENARD B. L.

    J. Org. Chem. 50, 3666, 1985

    被引用文献6件

  • <no title>

    CHENARD B. L.

    J.Org.Chem. 51, 3561, 1986

    被引用文献3件

  • <no title>

    MURAKAMI M.

    J.Chem.Soc., Chem.Commun. 1990, 428

    被引用文献2件

  • <no title>

    ITO Y.

    J. Chem. Soc., Chem. Commun. 1986, 980

    被引用文献1件

  • <no title>

    ITO Y.

    Pure Appl. Chem. 62, 583, 1990

    被引用文献1件

  • <no title>

    TSUJI Y.

    J. Am. Chem. Soc. 113, 9368, 1991

    被引用文献3件

  • <no title>

    OBORA Y.

    J. Org. Chem. 60, 4647, 1995

    被引用文献1件

  • <no title>

    OBORA Y.

    Organometallics 12, 4697, 1993

    被引用文献2件

  • <no title>

    TAMAO K.

    J. Organomet. Chem. 146, 87, 1978

    被引用文献4件

  • <no title>

    MATSUMOTO H.

    J. Organomet. Chem. 199, 185, 1980

    被引用文献2件

  • <no title>

    SAKURAI H.

    Chem. Lett. 1975, 887

    被引用文献4件

  • <no title>

    SAKURAI H.

    J. Organomet. Chem. 264, 229, 1984

    被引用文献2件

  • <no title>

    ITO Y.

    J. Org. Chem. 56, 1948, 1991

    被引用文献15件

  • <no title>

    YAMASHITA H.

    Chem. Lett. 1991, 241

    被引用文献11件

  • <no title>

    WATANABE H.

    J. Organomet. Chem. 186, 51, 1980

    被引用文献5件

  • <no title>

    MATSUMOTO H.

    J. Organomet. Chem. 199, 43, 1980

    被引用文献2件

  • <no title>

    WATANABE H.

    J. Organomet. Chem. 216, 149, 1981

    被引用文献4件

  • <no title>

    SAKURAI H.

    J. Am. Chem. Soc. 97, 931, 1975

    被引用文献8件

  • <no title>

    MURAKAMI M.

    J. Am. Chem. Soc. 113, 3987, 1991

    被引用文献5件

  • <no title>

    HAYASHI T.

    Organometallics 9, 280, 1990

    被引用文献6件

  • <no title>

    TSUJI Y.

    Organometallics 11, 2353, 1992

    被引用文献4件

  • <no title>

    OBORA Y.

    Organometallics 12, 2853, 1993

    被引用文献2件

  • <no title>

    OBORA Y.

    J. Am. Chem. Soc. 115, 10414, 1993

    被引用文献7件

  • <no title>

    idem

    J. Am. Chem. Soc. 117, 9814, 1995

    被引用文献1件

  • <no title>

    TSUJI J.

    Palladium Reagents and Catalysts, 290-422, 1995

    被引用文献1件

  • <no title>

    TSUJI Y.

    J. Org. Chem. 61, 5779, 1996

    被引用文献3件

  • <no title>

    TSUJI Y.

    J. Org. Chem. 58, 3607, 1993

    被引用文献1件

  • <no title>

    TSUJI Y.

    Organometallics 17, 4835, 1998

    被引用文献1件

  • <no title>

    TSUJI Y.

    J. Org. Chem. 58, 16, 1993

    被引用文献1件

  • <no title>

    MITCHELL T. N.

    J. Organomet. Chem. 304, 257, 1986

    被引用文献2件

  • <no title>

    KILLING H.

    Organometallics 3, 1318, 1984

    被引用文献2件

  • <no title>

    PIERS E.

    J. Chem. Soc., Chem. Commun. 1986, 626

    被引用文献3件

  • <no title>

    TSUJI Y.

    J. Chem. Soc., Chem. Commun. 1992, 1000

    被引用文献2件

  • <no title>

    OBORA Y.

    J. Chem. Soc., Perkin Trans 1, 599, 1995

    被引用文献1件

  • <no title>

    YAMASHITA H.

    Chem. Lett. 1990, 1477

    被引用文献1件

  • <no title>

    OZAWA F.

    Organometallics 13, 3237, 1994

    被引用文献7件

  • <no title>

    SUGINOME M.

    Bull. Chem. Soc. Jpn. 69, 289, 1996

    被引用文献6件

  • <no title>

    MURAKAMI Y.

    J. Am. Chem. Soc. 117, 6408, 1995

    被引用文献1件

  • <no title>

    AKHTAR H.

    J. Organomet. Chem. 22, 233, 1970

    被引用文献1件

  • <no title>

    WEICHMANN H.

    J. Organomet. Chem. 238, C49, 1982

    被引用文献1件

  • <no title>

    CHATT J.

    J. Chem. Soc. A 1970, 1343

    被引用文献1件

  • <no title>

    EABORN C.

    J. Chem. Soc., Dalton Trans. 1975, 2212

    被引用文献2件

  • <no title>

    PIDCOCK A.

    J. Organomet. Chem. 66, 23, 1974

    被引用文献1件

  • <no title>

    TSUJI Y.

    Organometallics 17, 507, 1998

    被引用文献6件

  • <no title>

    OKINOSHIMA H.

    J. Am. Chem. Soc. 94, 9263, 1972

    DOI 被引用文献11件

  • <no title>

    CARLSON C. W.

    Organometallics 2, 1801, 1983

    DOI 被引用文献5件

  • <no title>

    TAMAO K.

    J. Organomet. Chem. 114, C19, 1976

    被引用文献9件

  • <no title>

    OBORA Y.

    J. Am. Chem. Soc. 118, 10922, 1996

    DOI 被引用文献6件

各種コード

  • NII論文ID(NAID)
    10008819374
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    5301707
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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