ＦＡＭＳＯの化学

• 小倉 克之

  千葉大学工学部合成化学科

書誌事項

タイトル別名

• Chemistry of FAMSO
• FAMSO ノ カガク

抄録

During our investigation to search useful derivatives of dimethyl sulfoxide, we encountered a new sulfoxide, methyl methylthiomethyl sulfoxide which was also named formaldehyde dimethyl dithioacetal S-oxide. Now, this compound is designated conveniently as “FAMSO” by abbreviating he latter name.<BR>FAMSO was first synthesized by substitution of chloromethyl methl sulfoxide with a methanethiolate anion and it was later found that this compound could be more easily produced by oxidation of formaldehyde dimethyl dithioacetal with hydrogen peroxide. To date, many papers on organic syntheses using FAMSO have been published and it has appeared to be a versatile reagent for making a variety of organic compounds such as aldehydes, cyclic or acyclic ketones, α-hydroxy aldehydes, α-amino acids, α-keto acids, and α-arylalkanoic acids.<BR>This review will disclose the details of the production of FAMSO and its utilization for organic syntheses.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 37 (11), 903-913, 1979

  公益社団法人 有機合成化学協会

キーワード

• Organic Chemistry

詳細情報

• CRID: 1390001205279331328
• NII論文ID: 130000924215
• NII論文ID: 10008820004
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.37.903
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 2070054
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I2070054
• 本文言語コード: ja
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